What are the Reasons Why Refractory Bricks Can Resist High Temperatures?

Refractory bricks are inorganic non-metallic materials with a refractory degree of not less than 1580°C. It is a basic material for high-temperature technology, a structural material for masonry kilns and other equipment, and a functional material for manufacturing certain high-temperature containers and components or their special functions. The successful use of refractory bricks under high temperatures must have a good organizational structure, thermal properties, mechanical properties, and usability. That is to say, it has high refractoriness, load softening temperature, thermal shock resistance, and chemical erosion resistance so that it can withstand various powerful chemical changes and other effects, and meet the use requirements of thermal equipment and components. So, why can refractory bricks withstand high temperatures? RS Refractory Materials Manufacturer, a powerful refractory brick manufacturer, ensures that the refractory bricks can withstand high temperatures based on the raw materials of the refractory bricks and the characteristics of the molding and sintering process of the refractory bricks as inorganic non-metallic materials.

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    1. Raw materials for refractory bricks

    The raw materials used in the production of refractory bricks are generally natural ores. Refractory bricks with different properties are made by processing raw materials such as bauxite, silica, and magnesite. Such as aluminum-silicon refractory bricks, siliceous refractory bricks, and magnesia refractory bricks.

    Aluminum-silicon refractory bricks are produced using bauxite as raw material. Its main component is alumina. Hydrated alumina containing impurities is an earthy mineral that is insoluble in water and soluble in sulfuric acid and sodium hydroxide solutions. It is mainly used for smelting aluminum and making refractory materials. Because the refractoriness of high-alumina clinker is as high as 1780°C, it has strong chemical stability and good physical properties. The bauxite is purified at high temperature to produce a corundum main crystal phase with an alumina content greater than 90%, which can produce ultra-high temperature refractory bricks – fused zirconium corundum bricks.

    The raw material of silica refractory bricks is silica, and its main component is SiO2. The higher the content, the higher the refractory degree. The most harmful impurities are Al2O3, K2O, Na2O, etc. Silica bricks are made from natural silica as raw material, plus an appropriate amount of mineralizing agent to promote the conversion of quartz in the body into tridymite. It is slowly fired at 1350-1430°C in a reducing atmosphere. It has high-temperature strength and the load softening temperature is 1620℃.

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      Magnesite is the main raw material for making magnesite refractory bricks. Its basic component is MgO. Magnesium oxide has high refractory insulation properties. It can be transformed into crystals after being burned at high temperatures above 1000°C and becomes sintered magnesia when the temperature rises to 1500-2000°C. Then it can be made into magnesia bricks or magnesia ramming materials after being crushed to a certain particle size or powder. Magnesia refractory bricks are alkaline refractory bricks, which have strong energy resistance to alkaline slag but cannot resist the erosion of acidic slag. The refractoriness is above 2000℃, but its load softening point is only 1500℃, and its thermal shock stability is poor.

      1. Refractory bricks are inorganic non-metallic materials

      Inorganic non-metallic materials, organic polymer materials, and metallic materials are listed as the three major materials. Common inorganic non-metallic materials are characterized by high compressive strength, hardness, high-temperature resistance, and corrosion resistance. In addition, ceramics have excellent corrosion resistance, and refractory materials have excellent properties in heat protection and insulation. These are incomparable to metal materials and polymer materials. However, compared with metal materials, it has low breaking strength and lacks ductility. Compared with polymer materials, they have higher density and complex manufacturing processes.

      1. Forming and sintering of refractory bricks

      The production process of refractory bricks is through mineral crushing-raw material mixing-mechanical molding-high temperature firing. This process finally produces a product that can withstand high temperatures. The sintering temperature of the green body passing through the high-temperature tunnel kiln will be higher than the load-softening temperature of the product. Generally, the sintering temperature is above 1500℃, the refractoriness is above 1770℃, and the high-temperature resistance is good. Refractory bricks are mainly used to build kiln linings such as steelmaking electric furnaces, glass furnaces, and cement rotary furnaces.

      To summarize, there are three main reasons why refractory bricks can resist high temperatures. ① The raw minerals used in refractory bricks have high refractoriness. ② As an inorganic non-metallic material, the level of its use is determined by the level of raw materials. ③ The finished body has passed through a high temperature of over 1500°C in a high-temperature tunnel kiln, so the refractory bricks can resist high temperatures and are suitable for use in high-temperature kiln linings.

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        Performance advantages of low porosity refractory bricks

        Clay refractory products are extremely versatile and are made of high-quality raw materials. It is an indispensable refractory material for various industrial kilns. Low-porosity clay bricks were originally designed and widely used in hot blast stoves and glass kiln regenerators. Nowadays, it is widely used in lime kilns due to its good density and good resistance to chemical corrosion, especially alkali corrosion.

        Low-porosity clay bricks are refractory products made from high-quality burnt gemstones as the main raw material, and their performance has been fully upgraded. The performance advantages of low porosity refractory bricks include.

        1. Strong corrosion resistance.
        2. Low porosity and high density.
        3. High mechanical strength.
        4. Strong anti-penetration ability.
        5. High strength and high fire resistance.
        6. The organization is dense.
        7. Good thermal shock stability and resistance to peeling.

        RS refractory brick manufacturer

        RS Refractory Brick Manufacturer is a powerful manufacturer of refractory brick production and sales. Our refractory brick products have an annual output of 60,000 tons, and the quality is reliable and guaranteed. We have also made certain breakthroughs in thermal insulation material products. It has contributed a small step forward for energy-saving and heat preservation of high-temperature industrial furnaces. Our RS company can provide comprehensive refractory services for high-temperature industrial furnaces. Our professional technical team can also provide suitable solutions for the lining of high-temperature industrial furnaces. Material design and construction of refractory linings, and turnkey refractory projects. Contact us to get a free quote and samples.

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          What Kind of Refractory Material is Used for the Lining of the Hydrogen Sulfide Incinerator?

          The working temperature in the furnace of the incinerator burning hydrogen sulfide is about 1150 ℃, and the working conditions are harsh. It belongs to an acidic combustion atmosphere, but the temperature of the furnace will reach 1400 ℃ due to the fluctuation of materials and air volume in actual production. The amount of hydrogen sulfide gas is very unstable, and every combustion fluctuation in the furnace is a big thermal shock to the furnace lining.

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            And this kind of acid gas furnace lining is made of refractory materials, so it is very important to resist acid corrosion and thermal shock stability. The main body of the furnace can adopt a three-layer structure. Corundum mullite bricks should be used for parts that are in direct contact with the flame. It is characterized by strong wear resistance and corrosion resistance. The middle layer can choose three grades of high alumina bricks. Because the working layer does not directly contact the flame, the flexibility of the three-grade high-alumina brick is relatively good. The outer layer can be used as an insulation layer, and high-aluminum heat-insulating refractory bricks are used to keep the temperature down and reduce the temperature of the outer wall of the steel shell.

            • Corundum mullite brick is a refractory product composed of mullite as the main crystal phase and corundum phase, which is sintered at a high temperature of 1650-1750 °C. It has good high-temperature strength, high-temperature creep resistance, thermal shock resistance, and corrosion resistance.
            • The third-grade high-alumina brick is a series of aluminum products made of high-alumina raw materials and clay as a binder fired at a temperature of 1400°C. High thermal stability, and strong flexibility.
            • Lightweight high alumina brick. It has the characteristics of small bulk density, large porosity, low thermal conductivity, and specific heat capacity, and has good thermal insulation performance for heat insulation layers. In the case of slow heat dissipation, it can save fuel and reduce the temperature of the steel shell.

            The incinerator burning hydrogen sulfide is one of the rare furnace types, so the corundum mullite brick in the refractory brick used for its refractory lining is a high-grade refractory material. High-alumina bricks are neutral materials, and lightweight high-alumina bricks are used as a three-layer masonry lining to effectively improve the corrosion resistance of the incinerator. The refractory mortar of the same material is used for masonry during construction to ensure the long-term safe and reliable operation of the incinerator.

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              How to Choose Refractory Lining for Blast Furnace?

              How to choose refractory lining for blast furnace? In the design of refractory materials for blast furnaces, the different working conditions and erosion mechanisms of each part of the blast furnace should be fully considered, combined with the conditions of the original fuel, and the refractory materials should be selected in a targeted manner. The high-quality Refractory Lining for Blast Furnace, which can not only improve the service life of the blast furnace but also greatly save the production cost.

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                Therefore, according to the different working conditions of different parts of the blast furnace, the selection of refractory lining for blast furnace used in each part is as follows.

                (1) Furnace bottom, hearth, taphole area, and tuyere belt.

                The development of longevity technology in the hearth and hearth bottom has gone through a long process. The mainstream models of the entire hearth and hearth bottom structure are the “carbon + ceramic composite hearth and hearth bottom” structure and the “carbonaceous hearth + integrated hearth bottom” structure, these two technical systems.

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                  The heat-resistant castable is used below the furnace bottom water-cooling pipe centerline to the elevation of the heat-resistant foundation pier top. Carbon refractory ramming material is used between the centerline of the furnace bottom water-cooled pipe and the first layer of fully covered carbon brick. The first, second, and third layers are covered with semi-graphite carbon blocks, and the fourth layer is covered with microporous carbon bricks. There are also carbon bricks and ultra-microporous carbon bricks, the bottom of the furnace is made of two layers of ceramic pads, and the hearth is made of ceramic walls. The ceramic is beneficial to the heat preservation of the hearth slag and is conducive to saving the coke ratio and active hearth.

                  By adopting strong cooling measures in which the furnace bottom water cooling tube is buried under the furnace bottom brick, and the building method of the carbon furnace and ceramic. The goal of reducing erosion rate and longevity of blast furnace can be achieved.

                  The taphole area is built with carbon composite bricks. A composite brown corundum combined brick structure is adopted in the tuyere area. Its anti-slag iron corrosion and thermal shock resistance are good, the overall performance is good, and it has good protection for the tuyere-cooler casings. At the same time, it supports the refractory brick lining of the furnace belly.

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                    (2) The area of furnace belly, furnace waist, and furnace body.

                    A thin furnace lining structure with an integrated refractory brick wall is adopted, and the lining of cast iron cooling plate refractory brick is integrated with the cooling wall by cold setting. The production practice of the steel mill proves that this design structure can fully meet the normal service life of the blast furnace for 12-15 years.

                    The furnace belly, furnace waist, and lower part of the furnace body are inlaid with silicon carbide bricks combined with silicon nitride. The middle of the furnace body is made of fired microporous aluminum carbon brick. The middle and upper parts of the furnace body are lined with phosphoric acid-impregnated high-density clay bricks.

                    (3) Refractories for furnace throat

                    Furnace throat plays a role in protecting furnace lining and reasonable cloth. This area is mainly affected by direct impact and friction from blast furnace incoming materials. Because the temperature of this part is not high, about 400~500℃, the refractory materials used are mostly dense clay bricks, high alumina bricks, and sillimanite bricks. But the service life is still short, so it is also protected by wear-resistant and impact-resistant cast steel bricks.

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                      (4) Furnace top and riser.

                      Spraying materials with strong CO corrosion resistance and high thermal flexural strength.

                      (5) Between the cooling stave and the furnace shell.

                      The grout is pressed into the refractory mortar without water.

                      Rongsheng refractory brick manufacturer

                      Rongsheng is a refractory manufacturer with more than ten years of production and sales experience. Our refractory brick and refractory castable production lines are equipped with advanced production equipment. Moreover, our experienced technical engineers of refractory materials always pay attention to the development of refractory materials and customize refractory products for customers’ refractory linings. Our refractory products have been sold to more than 60 countries around the world, such as Malaysia, South Africa, India, Indonesia, Pakistan, Netherlands, Kuwait, Kenya, Russia, United States, etc. If your blast furnace needs refractory bricks or refractory castables. Please contact us with your details requirements, we will provide you with efficient refractory service.

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